Magnesium, Mg, is a silvery metallic alkaline earth element
belonging to
Group IIa of the periodic table.
- Atomic Number : 12
- Atomic Mass : 24
- Melting Point : 651 degC
- Boiling Point : 1107 degC
- Density : 1.7
Discovery
Magnesium was discovered by Bussy in 1828AD.
Magnesium was first isolated by Sir Humphery
Davy in 1808AD as an impure metal.
Occurrence
Magnesium is found as its oxide, being a constituent of rocks in different
ore forms.
- In igneous rocks, it occurs as olivine, (MgFe)2SiO4.
- In sedimentary rocks, it occurs as the carbonate, magnesite, and
as the mixed carbonate, dolomite.
Magnesium also occurs as soluble salts including epsom salts, which is
found in mineral waters and in hard waters.
Magnesium also occurs as
- kieserite, MgSO4.H2O,
- schonite, K2SO4.MgSO4.6H2O,
- kainite, MgSO4.KCl.3H2O, and
- carnallite, MgCl2.KCl.6H2O, in the salt beds at Strassfurt in Germany.
Manufacture
Magnesium is prepared by the electrolysis of fused anhydrous magnesium
chloride.
2 MgCl2 ==> 2 Mg + 2 Cl2
Magnesium is also prepared by heating magnesium oxide with carbon above
1000 degC.
MgO + C ==> Mg + CO
Properties
Magnesium is
Uses
Magnesium is used
- as a component in light alloys in the aircraft industry, because of
its low density and many of these alloys are resistant to corrosion,
- in the nuclear industry in "Magnox" alloys as it is transparent
to thermal neutrons,
- in the manufacture of Grignard Reagents in organic chemistry, and
- in medicine, where magnesium oxide and magnesium carbonate are
used as antacids.
Detection and Analysis
Magnesium is detected and quantified by precipitating it as the
insoluble magnesium ammonium phosphate.
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