Back-Titrations

Back-titrations may be used in volumetric analysis where direct titrations cannot be used for technical reasons. For example, when a compound is not soluble in water, or where it contains impurities which interfere with direct titration, an excess of the titrant may be added, and the excess then determined by titration (i.e. by back titration).


Balanced Chemical Equations

Balanced chemical equations describe the chemical changes which occur during the course of a chemical reaction, and
  1. Identifies reactants and products,
  2. Gives the correct composition of each reactant and product,
  3. Gives relative numbers of atoms, ions and molecules involved, and
  4. Gives relative weights of substances.
For example, the following equation indicates that two moles of hydrogen react with one mole of oxygen to form two moles of water.

            2 H2    +    O2     ==>    2 H2O


Base

A base is a substance, which reacts with an acid to form salt and water only. Arrhenius in his researches into the behaviour of electrolytes in solution proposed that a base is a substance which provides hydroxide ions in aqueous solution as a result of dissociation and ionisation. Later, Lewis introduced the idea that acids and bases had a reciprocal relationship and he introduced the concept of Lewis conjugate acid/base pairs.

A Lewis Acid (conjugate) is an electron pair acceptor and a Lewis Base (conjugate) is an electron pair donor.


                NH3     +     H3O(+)    ==>       NH4(+)    +     H2O
                Lewis        Lewis                Lewis           Lewis	 
                Base         Acid                 Acid            Base
In particular, water and the Hydrated Proton, H3O(+), are a 
conjugate acid-base pair, as the hydrated proton is able to 
donate a proton to water and water is able to receive the 
proton.	

                        H(+)	+	H2O	==>	H3O(+)	
                     Lewis		Lewis
                     Base		Acid

Basic Oxides

Basic oxides are the oxides of metals (e.g. sodium oxide and copper oxide), and they react with water to form alkaline solutions.

                             Na2O   +   H2O   ==>   2 NaOH	

Basic oxides form salts and water on reaction with acids.	

                             Na2O   +   2HCl   ==>   2 NaCl   +   H2O	
          
                           CuO   +   2 HNO3   ==>   Cu(NO3)2  +  H2O   	

Strongly basic oxides form compounds with water containing a metal combined directly to a hydroxyl group, they are therefore called hydroxides. The hydroxides of sodium and potassium are also called alkalis.


                                 K2O   +   H2O   ==>   2 KOH


beta-Particles

A beta-particles is the charged particle emitted from the nucleus of an atom during its spontaneous decay.


Biochemical Oxygen Demand

Biochemical oxygen demand, BOD, is the amount of oxygen taken up by microorganisms to decompose organic waste matter which is present in water.

Biochemical oxygen demand is therefore used as an empirical measure of the amount of certain biologically degradable waste types of organic pollutant that are present in water.

Biochemical oxygen demand is calculated by keeping a sample of water containing a known amount of oxygen for five days at 20 degC in the dark. The oxygen content is measured again after this time.

A high biochemical oxygen demand indicates the presence of a large number of microorganisms, consuming large amounts of organic matter, which suggests a high level of pollution.

There is an empirical relationship between the two determinants that describe pollution load in a sample (i.e. between biochemical oxygen demand and chemical oxygen demand).


Biological Importance of Metals

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Biological Oxidation

Biological oxidation involved the mediation of biological species in the Oxidation of organic matter. In general, biological oxidation proceeds by enzyme catalysis.


Bohr Model of the Atom

The Bohr model of the atom uses the particle theory of the electron to explain the spectrum of the hydrogen atom.

In 1913 AD, Neils Bohr used the particle theory of the electron to explain the spectrum of the hydrogen atom.

Bohr postulated that the hydrogen atom consisted of a central positive nucleus round which an electron moved in atomic orbit and that an electron may only be found in one of a limited number of those orbits.

The number of orbits was limited, each corresponding to a definite energy level, where the angular momentum, mvr, of the electron in its path about the nucleus must always be equal to nh/2( (where n = 1, 2, 3...) Thus,


			mvr = nh/2	

where	
m	is the mass of the electron	
v	is the velocity	
r	is the radius of the orbit	
n	is an integer called a Quantum Number used to characterising the 
orbit and 	
h	is Plank's constant. 
Bohr also postulated that as long as an electron remains in a given orbit it neither absorbs nor emits energy, and that movement of an electron from a low energy state to a higher energy state involves absorption of energy, and movement of an electron from a higher energy state to a lower energy state involves emission of energy in the form of radiation.

Thus, the lines in the spectrum of hydrogen are due to electrons falling from the excited state (i.e. a higher energy level) to the ground state (i.e. the lower energy). Each line in the hydrogen spectrum is ascribed to the transfer of an electron from an orbit of a high n value to one of a lower n value.


Boiling Point

The boiling point of a liquid is the temperature at which the vapour pressure of the liquid is equal to the atmospheric pressure. The liquid changes from the liquid state to the gas state at its boiling point.


Boltzmann Constant

The Boltzmann constant, k, named after the Austrian physicist Ludwig Boltzmann (1844-1906), is the ratio of the universal gas constant, R, to the Avogadro constant, Na.

The Boltzmann constant, k, is as the gas constant per molecule.


	k     	=     	R / NaNA     	=     	1.380622 * 10^-23 JK-1


Boyle's Law

Boyle's Law, is the empirical relationship, which states that given a fixed mass of gas at constant temperature, its volume is inversely proportional to its pressure.

Boyle's Law applies to ideal gases only. Real gases deviate considerable form this ideal relationship.

It is called after the Irish physicist and chemist Robert Boyle


Bomb Calorimeter

A bomb calorimeter is an apparatus used for measuring heats of combustion. It consists of a strong container in which the sample is sealed with excess oxygen and ignited electrically. The heat of combustion at constant volume can be calculated from the resulting rise in temperature of the calorimeter and its contents.


Bond

A bond (i.e. chemical bond) is the attractive force between the atoms in a molecule, which keeps the molecule together.

A chemical bond between atoms involves the overlap of an atomic orbital from each of the two atoms involved in the bond and keeps the molecule intact as an entity.


Bond Energy

Bond Energy is the amount of energy associated with a bond in a chemical compound.

For example, in methane the bond energy of the carbon to hydrogen bond is one quarter of the Enthalpy of the synthesis process.


		CH4(g)     ==>     C(g)    +    4 H(g)	

Bond energies can be calculated from the standard enthalpy of formation of the compound and from the enthalpies of atomisation of the elements. Energies calculated in this way are called average bond energies or bond energy terms. They depend to some extent on the molecule chosen; the C-H bond energy in methane will differ slightly from that in ethane. The bond dissociation energy is a different measurement, being the energy require to break a particular bond.


Bond Pairs

Bond pairs are the pairs of electrons involved in covalent bonds, or the unbonding lone pair of electrons which exist in a single sub-orbital of the central atom of a molecule.


Bonding and Structure in Group VI Oxides

Silica, SiO2, forms a giant tetrahedral molecule, which is bonded covalently. Every silicon atom is attached to four oxygen atoms, and every oxygen atom is common to two SiO4 tetrahedral.

Carbon, C, can form double bonds and Carbon Dioxide, CO2, is an example of a compound that exist as discrete molecules. However, since silicon cannot form double bonds, Silicon Dioxide, SiO2, (i.e. Silica) only forms an infinite three-dimensional tetrahedral structure.


Born-Haber Cycle

The Born-Haber cycle is a cycle of reactions used to calculate the lattice energies of ionic crystalline solids. Lattice Energy cannot be measured directly by experimental methods.


Bragg's Law

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